《干式循环流化床烟气脱硫技术》

核心提示: 干式循环流化床烟气脱硫技术是20世纪80年代后期发展起来的一种新的干法烟气脱硫技术,该技术具有投资少、占地小、结构简单、易于操作,兼

 干式循环流化床烟气脱硫技术是20世纪80年代后期发展起来的一种新的干法烟气脱硫技术,该技术具有投资少、占地小、结构简单、易于操作,兼有高效除尘和烟气净化功能,运行费用低等优点。因而,国家电站燃烧工程技术研究中心和清华大学煤的清洁燃烧技术国家重点实验室分别对该技术的反应机理、反应过程的数学模型等进行了理论和实验研究。其工艺流程如下:

  从煤粉燃烧装置产生的实际烟气通过引风机进入反应器,再经过旋风除尘器,最后通过引风机从烟囱排出。脱硫剂为从回转窑生产的高品质石灰粉,用螺旋给粉机按给定的钙硫比连续加入。旋风除尘器除下的一部分脱硫灰经循环灰斗和螺旋给灰机进入反应器中再循环。在文丘里管中有喷水雾化装置,通过调节水量来控制反应器内温度。

  干式循环流化床烟气脱硫技术在烟气中SO2浓度较低的情况下尤其适用。它具备以下特点:

  (1)锅炉飞灰作为循环物料,反应器内固体颗粒浓度均匀,固体内循环强烈,气固混合、接触良好,气固间传热、传质十分理想。

  (2) 反应塔中由于颗粒的水分蒸发与水分吸附、固体颗粒之间的强烈接触摩擦,造成气、固、液三相之间极大的反应活性和反应表面积,对于烟气SO2的去除有非常理想的效果。

  (3) 固体物料被反应器外的高效旋风分离器和除尘器收集,再回送至反应塔,使脱除剂反复循环,在反应器内的停留时间延长,从而提高了脱除剂的利用率,降低了运行成本。

  (4) 通过向反应器内喷水,使烟气温度降至接近水蒸汽分压下的饱和温度,提高脱硫效率。

  (5) 反应器不易腐蚀、磨损。(6) 系统中的粉煤灰对脱硫反应有催化作用。

  该技术已经在国家电站燃烧工程技术研究中心和清华大学煤的清洁燃烧技术国家重点实验室分别建立了烟气循环流化床脱硫热态试验装置,为干式循环流化床烟气脱硫技术开发提供了新的理论依据与基础数据。

  目前对现有的机组进行烟气脱硫技术改造方面投入了大量的精力,正在多个领域展开研究工作,其中在干法烟气脱硫方面研究较多的是循环流化床烟气脱硫技术及电子射线辐射法烟气脱硫技术,电晕法烟气脱硫技术目前研究的也较多。烟道气脱硫技术最显着改造之一是吸收器规格的增大,采用单个吸收器,据报道安装一台脱硫装置可服务于两台大型锅炉的烟气脱硫装置,以这种方式增大设备规格,大大降低了投资成本。

  研究与开发出一种新的烟气脱硫装置是烟气脱硫技术的发展趋势之一。其研发方向为SO2脱硫率高、可靠性强、辅助耗电低、采用单个吸收器、副产品可售或可利用,为保障这些技术要求,应该在脱硫技术的工艺、设备和材料方面进行进一步研究。

上海电气
电力月刊109期
循环流化床锅炉技术2016年会
火电厂金属材料与焊接技术交流2016年会

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